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Synthesis, Characterization and Study of Schiff Base Ligand Type N2 and Metal Complexes with Di Valence Nickel, Copper and Zinc
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| Author:
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TAHA H. ALNASRAWI, SHATHA ABD_ALAMEER JAWAD, HAMIDA EDAN SALMAN, MOHAMMED RIDHA AL-HAIDERI
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| Abstract:
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The di dentate ligand type N2 have been prepared through two steps. The first included the reaction between one equivalent of ethylenediamine with tow equivalent of benzaldehyde the second included the reaction of first step precursor with one equivalent of sodiumborontetrahydride (NaBH4), to obtained the target ligand. Ni+2, Cu+2, Zn+2 from there action of the ligand Complexes were prepared with metal ions 1:1 ratio, the proposed compounds were characterized by FT-IR, UV-Vis, NMR for ligand, C.H.N spectroscopies, the biological activity as well as the molar conductivity and magnetic the success stability. Suggested geometry around the Zinc and Copper ions is tetrahedral and square planer around nickel ion.
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| Keyword:
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ethylene di amine, Schiff base, Metal complex, benzaldehyde, Sodiumborontetrahydride
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| EOI:
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-
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| DOI:
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https://doi.org/10.31838/ijpr/2020.SP1.200
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| Download:
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Request For Article
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