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Synthesis,Characterization , Antibictrial and theoretical Studies of New 1,1'-(1,4-phenylene)bis(N-(4H-1,2,4-triazol-4-yl)methanimine)With some transition metal ions
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| Author:
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, HAMEEDI N. NASER, ZAINAB M. KAREEM
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| Abstract:
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A new ligand 1,1'-(1,4-phenylene)bis(N-(4H-1,2,4-triazol-4-yl)methanimine) and its Co(IIl) , Ni(ll) and Cu (ll) complexes were synthesized . the new ligand and its complexes have been characterization on the basis their spectra of H1NMR, mas, Fourier transform infrared (FTIR), as well as magnetic susceptibility, elemental analysis [CHN], atomic absorption and conductance measurements. The Gaussain 09 program have been used for theoretical study of Molecular properties by using B3LYP/6-31G* level of theory. Hyperchem 8 have been used for theoretical accounts using PM3 method to study the electrostatic potential that provided good information about the complexity site. Of the result obtained we can suggested octahedral geometries for Co(???) and square planer geometry for Ni(??) and Cu(??). The ligand and its complex gave a good activity antibacterial.
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| Keyword:
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ligand, complexes, characterization, triazole, antibacterial.
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| EOI:
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-
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| DOI:
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https://doi.org/10.31838/ijpr/2020.SP2.574
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| Download:
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